The Effect of Nano Materials on the Rheological Properties of Asphalt Binder
Received: 28 December 2024 | Revised: 14 January 2025 | Accepted: 25 January 2025 | Online: 24 February 2025
Corresponding author: Rana A. Yousif
Abstract
This study investigates the effects of nano-silica, nano-chitosan, and nano-clay as asphalt binder modifiers, focusing on their physical and rheological properties. The nanomaterials were incorporated at concentrations of 2.5%, 5.0%, 7.5%, and 10% by weight. This research was driven by the growing adoption of nanomaterials, many of which are known for their toxicity and environmental impact. The results demonstrated a significant improvement in both physical and rheological properties, particularly in rutting resistance. Nano-silica demonstrated the greatest enhancement, leading to a reduction in permeability values, an increase in softening point, viscosity, and overall resistance to permanent deformation. Nano-chitosan exhibited a similar trend but with slightly lower performance values than nano-silica. Nano-clay provided the least improvement, though it still contributed to increased asphalt binder stiffness and reduced temperature sensitivity. Overall, the findings confirm that nano-silica, nano-chitosan, and nano-clay can improve asphalt binder properties, extending pavement lifespan and performance under increasing traffic demands. Further studies are recommended to explore the long-term aging resistance, fatigue behavior, and field applications of these nanomaterial-modified asphalt binders.
Keywords:
nano materials, chitosan, nano silica, nano clay, physical properties, rheological propertiesDownloads
References
Z. You et al., "Nanoclay-modified asphalt materials: Preparation and characterization," Construction and Building Materials, vol. 25, no. 2, pp. 1072–1078, Feb. 2011.
A. R. Ghasemi, T. Parhizkar, and A. A. Ramezanianpour, "Influence of colloidal nano-SiO2 addition as silica fume replacement material in properties of concrete," in Second international conference on sustainable construction materials and technologies, Ancona, Italy, 2010, pp. 28–30.
A. Parviz, "Nano materials in asphalt and tar," Australian Journal of Basic and Applied Sciences, vol. 5, no. 12, pp. 3270–3273, 2011.
S. G. Jahromi and A. Khodaii, "Effects of nanoclay on rheological properties of bitumen binder," Construction and Building Materials, vol. 23, no. 8, pp. 2894–2904, Aug. 2009.
C. Fang, R. Yu, S. Liu, and Y. Li, "Nanomaterials Applied in Asphalt Modification: A Review," Journal of Materials Science & Technology, vol. 29, no. 7, pp. 589–594, Jul. 2013.
M. Abdelrahman, D. R. Katti, A. Ghavibazoo, H. B. Upadhyay, and K. S. Katti, "Engineering Physical Properties of Asphalt Binders through Nanoclay–Asphalt Interactions," Journal of Materials in Civil Engineering, vol. 26, no. 12, Dec. 2014, Art. no. 04014099.
M. J. Khattak, A. Khattab, H. R. Rizvi, and P. Zhang, "The impact of carbon nano-fiber modification on asphalt binder rheology," Construction and Building Materials, vol. 30, pp. 257–264, May 2012.
H. Ezzat, S. El-Badawy, A. Gabr, E.-S. I. Zaki, and T. Breakah, "Evaluation of Asphalt Binders Modified with Nanoclay and Nanosilica," Procedia Engineering, vol. 143, pp. 1260–1267, Jan. 2016.
H. Yao et al., "Performance of asphalt binder blended with non-modified and polymer-modified nanoclay," Construction and Building Materials, vol. 35, pp. 159–170, Oct. 2012.
H. Yao et al., "Rheological Properties and Chemical Bonding of Asphalt Modified with Nanosilica," Journal of Materials in Civil Engineering, vol. 25, no. 11, pp. 1619–1630, Nov. 2013.
H. Yao et al., "Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy," Construction and Building Materials, vol. 38, pp. 327–337, Jan. 2013.
X. X. Zhou, G. F. Zhang, R. M. Liu, and L. Zheng, "Molecular Simulations of Anti-Aging Mechanisms on Nano-LDHs Modified Asphalt," Key Engineering Materials, vol. 599, pp. 198–202, 2014.
M. F. ul Haq et al., "Carbon Nanotubes (CNTs) in Asphalt Binder: Homogeneous Dispersion and Performance Enhancement," Applied Sciences, vol. 8, no. 12, Dec. 2018, Art. no. 2651.
H. Zhang, J. Yu, and S. Wu, "Effect of montmorillonite organic modification on ultraviolet aging properties of SBS modified bitumen," Construction and Building Materials, vol. 27, no. 1, pp. 553–559, Feb. 2012.
J. V. S. de Melo, G. Trichês, and L. T. de Rosso, "Experimental evaluation of the influence of reinforcement with Multi-Walled Carbon Nanotubes (MWCNTs) on the properties and fatigue life of hot mix asphalt," Construction and Building Materials, vol. 162, pp. 369–382, Feb. 2018.
J. Rafi et al., "Performance Evaluation of Carbon Black Nano-Particle Reinforced Asphalt Mixture," Applied Sciences, vol. 8, no. 7, Jul. 2018.
J. M. L. Crucho, J. M. C. das Neves, S. D. Capitão, and L. G. de Picado-Santos, "Mechanical performance of asphalt concrete modified with nanoparticles: Nanosilica, zero-valent iron and nanoclay," Construction and Building Materials, vol. 181, pp. 309–318, Aug. 2018.
S. Tayh and A. Raheel, "The Effect of Filler Type on the Hot Mix Asphalt Behavior," Engineering and Technology Journal, vol. 29, no. 9, pp. 1701–1720, Oct. 2024.
S. Abd Tayh and R. A. Yousif, "Effect of blending speed and blade level on the properties of reclaimed rubber modified bitumen," ARPN Journal Enginnering and Applied Science, vol. 13, no. 21, pp. 8386–8392, 2018.
H. M. Alnaqib and R. W. Bazuhair, "Evaluation of HMA Modified with Titan Polymer," Engineering, Technology & Applied Science Research, vol. 13, no. 3, pp. 10725–10730, Jun. 2023.
S. A. Tayh, A. F. Jasim, A. M. Mughaidir, and R. A. Yousif, "Performance enhancement of asphalt mixture through the addition of recycled polymer materials," Discover Civil Engineering, vol. 1, no. 1, Sep. 2024, Art. no. 68.
S. H. Arif, N. M. Abdulah, T. A. Mohsin, and V. A. Musa, "Additives Influence on the Properties of Asphalt Binders: A Case Study," Engineering, Technology & Applied Science Research, vol. 13, no. 2, pp. 10565–10570, Apr. 2023.
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