Simulation and Experimental Study of the Optical Properties of Black Silicon Synthesized by Reactive Ion Etching
Received: 21 November 2025 | Revised: 23 December 2025 | Accepted: 3 January 2026 | Online: 5 February 2026
Corresponding author: Gagik Ayvazyan
Abstract
This work presents a combined numerical and experimental study of the optical properties of black Silicon (b-Si), which is synthesized by reactive ion etching. Finite-Difference Time-Domain (FDTD) simulations based on a periodic nanocone model were used to analyze how nanostructure geometry influences spectral absorption, reflectance, and transmittance. The modeling results show that nanocone heights in the range of 650-700 nm and dense packing conditions, where the base diameter approaches the periodicity, provide optimal broadband antireflection. Experimental measurements confirm a reduction of the average reflectance to below ~2–3% in the visible range (400-700 nm) for b-Si layers with heights around 670 nm, in good agreement with simulation trends. The results establish quantitative geometric design rules for the targeted fabrication of broadband antireflective silicon surfaces and demonstrate the potential of b-Si for applications in silicon solar cells, photodetectors, and other optoelectronic devices.
Keywords:
black silicon, solar cell, optical propеrties, morphology, FDTD simulationDownloads
References
S. Manzoor, M. Filipič, A. Onno, M. Topič, and Z. C. Holman, "Visualizing light trapping within textured silicon solar cells," Journal of Applied Physics, vol. 127, no. 6, Feb. 2020, Art. no. 063104. DOI: https://doi.org/10.1063/1.5131173
C. Huo, H. Fu, and K.-Q. Peng, "Inverted pyramid structures fabricated on monocrystalline silicon surface with a NaOH solution," Heliyon, vol. 10, no. 1, Jan. 2024, Art. no. e23871. DOI: https://doi.org/10.1016/j.heliyon.2023.e23871
C. Ji et al., "Recent Applications of Antireflection Coatings in Solar Cells," Photonics, vol. 9, no. 12, Dec. 2022, Art. no. 906. DOI: https://doi.org/10.3390/photonics9120906
N. Shanmugam, R. Pugazhendhi, R. Madurai Elavarasan, P. Kasiviswanathan, and N. Das, "Anti-Reflective Coating Materials: A Holistic Review from PV Perspective," Energies, vol. 13, no. 10, Jan. 2020, Art. no. 2631. DOI: https://doi.org/10.3390/en13102631
V. M. Rotshteyn, T. K. Turdaliev, and Kh. B. Ashurov, "On the Question of the Possibility of Using Nanocrystalline Porous Silicon in Silicon-Based Solar Cells," Applied Solar Energy, vol. 57, no. 6, pp. 480–485, Dec. 2021. DOI: https://doi.org/10.3103/S0003701X21060153
M. A. Almeshaal, B. Abdouli, K. Choubani, L. Khezami, and M. B. Rabha, "Study of Porous Silicon Layer Effect in Optoelectronics Properties of Multi-Crystalline Silicon for Photovoltaic Applications," Silicon, vol. 15, no. 14, pp. 6025–6032, Sept. 2023. DOI: https://doi.org/10.1007/s12633-023-02482-8
H. Khmissi, B. Azeza, M. Bouzidi, and Z. Al-Rashidi, "Investigation of an Antireflective Coating System for Solar Cells based on Thin Film Multilayers," Engineering, Technology & Applied Science Research, vol. 14, no. 3, pp. 14374–14379, June 2024. DOI: https://doi.org/10.48084/etasr.7375
G. Ayvazyan, H. Dashtoyan, and L. Hakhoyan, "Wide-Range Wavelength Light Scattering from Black Silicon Layers: Profits for Perovskite/Si Tandem Solar Cells," Physica Status Solidi (RRL) – Rapid Research Letters, vol. 19, no. 2, 2025, Art. no. 2400235. DOI: https://doi.org/10.1002/pssr.202400235
Z. Fan et al., "Recent Progress of Black Silicon: From Fabrications to Applications," Nanomaterials, vol. 11, no. 1, Jan. 2021, Art. no. 41. DOI: https://doi.org/10.3390/nano11010041
S. Wang, T. Xie, R. Liang, Y. Zhang, F.-J. Ma, D. Payne, G. Scardera, and B. Hoex, "An artificial-intelligence-assisted investigation on the potential of black silicon nanotextures for silicon solar cells," ACS Applied Nano Materials, vol. 5, no. 8, pp. 11636–11647, 2022. DOI: https://doi.org/10.1021/acsanm.2c02619
G. Ayvazyan, L. Hakhoyan, A. Vardanyan, H. Savin, and X. Liu, "Wetting Properties of Black Silicon Layers Fabricated by Different Techniques," Physica Status Solidi (RRL) – Rapid Research Letters, vol. 18, no. 8, 2024, Art. no. 2400072. DOI: https://doi.org/10.1002/pssr.202400072
K. Yee, "Numerical solution of initial boundary value problems involving Maxwell’s equations in isotropic media," IEEE Transactions on Antennas and Propagation, vol. 14, no. 3, pp. 302–307, 1966. DOI: https://doi.org/10.1109/TAP.1966.1138693
Ansys Lumerical FDTD: Simulation of Photonic Components. Ansys, Inc, 2025.
A. Deinega, S. Belousov, and I. Valuev, "Hybrid transfer-matrix FDTD method for layered periodic structures," Optics Letters, vol. 34, no. 6, pp. 860–862, 2009. DOI: https://doi.org/10.1364/OL.34.000860
K. Han and C.-H. Chang, "Numerical modeling of sub-wavelength anti-reflective structures for solar module applications," Nanomaterials, vol. 4, no. 1, pp. 87–128, 2014. DOI: https://doi.org/10.3390/nano4010087
X. Zhang et al., "Effects of Black Silicon Surface Morphology Induced by a Femtosecond Laser on Absorptance and Photoelectric Response Efficiency," Photonics, vol. 11, no. 10, Oct. 2024, Art. no. 947. DOI: https://doi.org/10.3390/photonics11100947
S. Kim, G. S. Jeong, N. Y. Park, and J.-Y. Choi, "Omnidirectional and broadband antireflection effect with tapered silicon nanostructures fabricated with low-cost and large-area capable nanosphere lithography," Micromachines, vol. 12, no. 2, 2021, Art. no. 119. DOI: https://doi.org/10.3390/mi12020119
M. Oproescu, A.-G. Schiopu, V. M. Calinescu, V.-G. Iana, N. Bizon, and M. Sallah, "Influence of Supplementary Oxide Layer on Solar Cell Performance," Engineering, Technology & Applied Science Research, vol. 14, no. 2, pp. 13274–13282, Apr. 2024. DOI: https://doi.org/10.48084/etasr.6879
T. P. Pasanen, H. S. Laine, V. Vähänissi, K. Salo, S. Husein, and H. Savin, "Impact of Standard Cleaning on Electrical and Optical Properties of Phosphorus-Doped Black Silicon," IEEE Journal of Photovoltaics, vol. 8, no. 3, pp. 697–702, Feb. 2018. DOI: https://doi.org/10.1109/JPHOTOV.2018.2806298
T. Rahman, R. S. Bonilla, R. Nawabjan, P. Wilshaw, and S. Boden, "Passivation of all-angle black surfaces for silicon solar cells," Solar Energy Materials and Solar Cells, vol. 160, pp. 444–453, 2017. DOI: https://doi.org/10.1016/j.solmat.2016.10.044
Downloads
How to Cite
License
Copyright (c) 2026 Gagik Ayvazyan, Arthur Aghabekyan

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with this journal agree to the following terms:
- Authors retain the copyright and grant the journal the right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) after its publication in ETASR with an acknowledgement of its initial publication in this journal.
