Advanced Correlations for Predicting Wax Precipitation in Crude Oil: A Study on Melting Point and Solid-State Transition Temperatures

Authors

  • Alfiya Khussainova Kazakh-British Technical University, Tole bi str., 59, Almaty, 050000, Kazakhstan
  • Jamilyam Ismailova Satbayev University, 22/5, Satbayev str., Almaty, 050000, Kazakhstan
  • Gulnaz Moldabayeva Satbayev University, 22/5, Satbayev str., Almaty, 050000, Kazakhstan
  • Bakbergen Bekbau KMG Engineering LLP, 8 Qonayev st., Astana, Z05H9E8, Kazakhstan
  • Dinara Delikesheva Satbayev University, 22/5, Satbayev str., Almaty, 050000, Kazakhstan
  • Nargiz Zhumanbetova Satbayev University, 22/5, Satbayev str., Almaty, 050000, Kazakhstan
  • Abdulakhat Ismailov Kazakh-British Technical University, Tole bi str., 59, Almaty, 050000, Kazakhstan
  • Aigul Bakesheva Satbayev University, 22/5, Satbayev str., Almaty, 050000, Kazakhstan
Volume: 15 | Issue: 2 | Pages: 21505-21517 | April 2025 | https://doi.org/10.48084/etasr.9644

Abstract

This study presents an in-depth investigation into the fusion properties, specifically the melting point and solid-state transition temperature, of crude oil samples from five distinct fields in Kazakhstan. These properties are critical for understanding and predicting wax precipitation, which poses significant challenges in the petroleum industry, particularly in cold climates where wax deposition can obstruct pipelines. Using advanced analytical techniques, including gas chromatography and pour point testing, new correlations were developed to more accurately predict these fusion properties for Kazakhstani crude oil. The proposed correlations outperform the existing models, offering closer alignment with the experimental data across a wide range of hydrocarbon compounds. The novelty of this research lies in its tailored approach, which integrates experimental data, existing predictive models, and Python programming to develop a region-specific solution for Kazakhstani crude oil. By addressing the limitations of generalized models, the study highlights the importance of adapting predictive frameworks to specific oil compositions and regional conditions. These findings have substantial implications for the optimization of crude oil transportation and storage in cold environments, where wax deposition is a prevalent issue. The improved accuracy of the proposed correlations enables better predictability of wax-related flow assurance problems, contributing to more efficient and safer operations in the oil and gas industry. Furthermore, this work establishes a robust methodological framework that can be extended to other crude oil types and operational scenarios, paving the way for advancements in predictive modeling of wax precipitation under diverse environmental conditions.

Keywords:

crude oil, wax precipitation, flow assurance, melting point, solid-state transition, correlation

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References

J. H. Hansen, Aa. Fredenslund, K. S. Pedersen, and H. P. Rønningsen, "A thermodynamic model for predicting wax formation in crude oils," AIChE Journal, vol. 34, no. 12, pp. 1937–1942, 1988.

R. Venkatesan, N. R. Nagarajan, K. Paso, Y.-B. Yi, A. M. Sastry, and H. S. Fogler, "The strength of paraffin gels formed under static and flow conditions," Chemical Engineering Science, vol. 60, no. 13, pp. 3587–3598, Jul. 2005.

K. W. Won, "Thermodynamics for solid solution-liquid-vapor equilibria: wax phase formation from heavy hydrocarbon mixtures," Fluid Phase Equilibria, vol. 30, pp. 265–279, Jan. 1986.

K. W. Won, "Thermodynamic calculation of cloud point temperatures and wax phase compositions of refined hydrocarbon mixtures," Fluid Phase Equilibria, vol. 53, pp. 377–396, Dec. 1989.

Z. Baishemirov, J.-G. Tang, K. Imomnazarov, and M. Mamatqulov, "Solving the problem of two viscous incompressible fluid media in the case of constant phase saturations," Open Engineering, vol. 6, pp. 742–745, Dec. 2016.

D. V. Nichita, L. Goual, and A. Firoozabadi, "Wax Precipitation in Gas Condensate Mixtures," SPE Production & Facilities, vol. 16, no. 4, pp. 250–259, Nov. 2001.

H. Pan, A. Firoozabadi, and P. Fotland, "Pressure and Composition Effect on Wax Precipitation: Experimental Data and Model Results," SPE Production & Facilities, vol. 12, no. 4, pp. 250–258, Nov. 1997.

J. Xue, C. Li, and Q. He, "Modeling of wax and asphaltene precipitation in crude oils using four-phase equilibrium," Fluid Phase Equilibria, vol. 497, pp. 122–132, Oct. 2019.

C. Lira-Galeana, A. Firoozabadi, and J. M. Prausnitz, "Thermodynamics of wax precipitation in petroleum mixtures," AIChE Journal, vol. 42, no. 1, pp. 239–248, 1996.

K. Schou Pedersen, P. Skovborg, and H. P. Roenningsen, "Wax precipitation from North Sea crude oils. 4. Thermodynamic modeling," Energy & Fuels, vol. 5, no. 6, pp. 924–932, Nov. 1991.

M. R. Riazi, Characterization and Properties of Petroleum Fractions. West Conshohocken, PA, USA: ASTM International, 2005.

J. A. P. Coutinho, "Predictive UNIQUAC: A New Model for the Description of Multiphase Solid−Liquid Equilibria in Complex Hydrocarbon Mixtures," Industrial & Engineering Chemistry Research, vol. 37, no. 12, pp. 4870–4875, Dec. 1998.

J. A. P. Coutinho, B. Edmonds, T. Moorwood, R. Szczepanski, and X. Zhang, "Reliable Wax Predictions for Flow Assurance," Energy & Fuels, vol. 20, no. 3, pp. 1081–1088, May 2006.

W. Chen, Z. Zhao, X. Zhang, and L. Wang, "Thermodynamic phase equilibria of wax precipitation in crude oils," Fluid Phase Equilibria, vol. 255, no. 1, pp. 31–36, Jul. 2007.

J. Yang, W. Wang, B. Shi, Q. Ma, P. Song, and J. Gong, "Prediction of wax precipitation with new modified regular solution model," Fluid Phase Equilibria, vol. 423, pp. 128–137, Sep. 2016.

J. C. M. Escobar-Remolina, "Prediction of characteristics of wax precipitation in synthetic mixtures and fluids of petroleum: A new model," Fluid Phase Equilibria, vol. 240, no. 2, pp. 197–203, Feb. 2006.

R. Dalirsefat and F. Feyzi, "A thermodynamic model for wax deposition phenomena," Fuel, vol. 86, no. 10, pp. 1402–1408, Jul. 2007.

A. R. S. Nazar, B. Dabir, and M. R. Islam, "A Multi-Solid Phase Thermodynamic Model for Predicting Wax Precipitation in Petroleum Mixtures," Energy Sources, vol. 27, no. 1–2, pp. 173–184, Jan. 2005.

E. Ghanaei, F. Esmaeilzadeh, and J. F. Kaljahi, "New Multi-Solid Thermodynamic Model for the Prediction of Wax Formation," International Journal of Chemical and Molecular Engineering, vol. 1, no. 5, pp. 48–53, 2007.

C. Ghotbi, M. H. Mashhadi, and B. T. Jafari, "Thermodynamic modeling of wax precipitation in crude oil based on PC-saft model," in 12th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Malaga, Spain, Jul. 2016, pp. 1058–1067.

M. Mansourpoor, R. Azin, S. Osfouri, and A. A. Izadpanah, "Study of wax disappearance temperature using multi-solid thermodynamic model," Journal of Petroleum Exploration and Production Technology, vol. 9, no. 1, pp. 437–448, Mar. 2019.

E. D. Ivanchina, E. N. Ivashkina, G. Yu. Nazarova, and G. Zh. Seitenova, "Influence of Feedstock Group Composition on the Octane Number and Composition of the Gasoline Fraction of Catalytically Cracked Vacuum Distillate," Petroleum Chemistry, vol. 58, no. 3, pp. 225–236, Mar. 2018.

L. Tugashova, R. Bazhenov, U. Abdyldaeva, I. Korosteleva, and E. Muromtseva, "A simulation modeling approach used in the crude oil refining process," Journal of Physics: Conference Series, vol. 2373, no. 6, Dec. 2022, Art. no. 062003.

E. Krivosheev and R. Sayakhov. Gas chromatography. Guidelines for laboratory work: Method, Kazan National Research Technological University, 2020

S. Rehman, "Machine Learning Guide for Petroleum Professionals: Part 1," TWA, Feb. 07, 2023. https://jpt.spe.org/twa/a-machine-learning-guide-for-petroleum-professionals-part-1.

W. B. Kay, "Density of Hydrocarbon Gases and Vapors at High Temperature and Pressure," Industrial & Engineering Chemistry Research, vol. 28, no. 9, pp. 1014–1019, 1936.

E. V. Asbaghi and M. Assareh, "Application of a sequential multi-solid-liquid equilibrium approach using PC-SAFT for accurate estimation of wax formation," Fuel, vol. 284, Jan. 2021, Art. no. 119010.

S. I. Eyitayo et al., "A Comparative Evaluation of Selected Correlations for Estimating Wax-Appearance Temperature of Crude Oils," in SPE Nigeria Annual International Conference and Exhibition, Aug. 2020, pp. 1–7.

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How to Cite

[1]
Khussainova, A., Ismailova, J., Moldabayeva, G., Bekbau, B., Delikesheva, D., Zhumanbetova, N., Ismailov, A. and Bakesheva, A. 2025. Advanced Correlations for Predicting Wax Precipitation in Crude Oil: A Study on Melting Point and Solid-State Transition Temperatures. Engineering, Technology & Applied Science Research. 15, 2 (Apr. 2025), 21505–21517. DOI:https://doi.org/10.48084/etasr.9644.

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